PUB2596
Waste Management Program fact sheet
Division of Environmental Quality Director: Art Goodin

This fact sheet provides general information to help pesticide applicators determine whether their leftover, unwanted pesticide is solid waste or hazardous waste and how to properly dispose of each type. Disposal is an important part of responsible pesticide use, as improperly disposed pesticide wastes can create serious hazards for human health and the environment. Businesses should refer to this fact sheet as general guidance only and should review appropriate state and federal laws and regulations before making the ultimate decision of how to manage waste pesticides.

Regulatory Citations

The federal hazardous waste regulations are in the Code of Federal Regulations, Title 40, Part 260 through Part 280 (40 CFR 260-280). The Missouri Hazardous Waste Law is in the Revised Statutes of Missouri (RSMo), Sections 260.350-260.575. The hazardous waste rules are in the Code of State Regulations, Title 10, Division 25 (10 CSR 25).

What is a pesticide waste?

Pesticide waste is any material that contains any concentration of pesticide declared a waste or can no longer be used for its intended purpose. This includes such things as: rinse material from containers and spray equipment, leftover spray solutions, excess pesticides, empty containers and banned, canceled or suspended pesticides.

Are all pesticide wastes considered hazardous wastes?

No, under federal regulations, commercial chemical products such as pesticides become "solid wastes" and thus, potentially hazardous wastes, at the point when the pesticide's holder (i.e., end-user, dealer, distributor or registrant) decides to discard them. If a pesticide product or the active ingredient of the product is listed in 40 CFR 261.31 or 261.33 (Table 1) or exhibits a hazardous waste characteristic identified in 40 CFR 261.21 through 261.24, it then becomes a hazardous waste at the point when its holder decides to discard it. Parts 261.21 through 261.24 identify the following criteria: ignitability, corrosivity, reactivity or toxicity characteristic. Most hazardous waste pesticides fall into the toxicity criteria due to the toxic organic properties.

An environmental consultant or hazardous waste disposal contractor can help make a hazardous waste determination for you to dispose of the waste pesticide properly. The Missouri Department of Natural Resources maintains a Licensed Hazardous and Infectious Waste Transporter List. The department also provides a list of Missouri Commercial Hazardous Waste Facilities - PUB0968 with permits to accept hazardous waste. It is always recommended to call several consultants/contractors when obtaining bids for disposal.
More ways to help determine if a pesticide is a hazardous waste include:

  • Checking the Material Safety Data Sheet for the pesticide
  • Talking to the product supplier or manufacturer.
  • Reading the product labels

How to dispose of pesticide classified as hazardous waste?

Businesses generating hazardous waste must follow federal and state laws and regulations, depending on the type and amount of hazardous waste generated. Publications summarizing hazardous waste regulations include Handbook for Small-Quantity Generators - PUB2174 and EPA’s guidance document, Typical Wastes Generated By Industry Sectors.

Determining how much hazardous waste pesticide is generated in any one month and accumulated at any one time is necessary information for determining generator requirements. Hazardous waste generator requirements is available at 10 CSR 25-5.262 and a summary of the regulations is available in a fact sheet titled Hazardous Waste Generator Status Guidance - PUB2224.

To avoid having to dispose of unused pesticide products, try to give the unneeded product away to someone who can use the product for its intended purpose, provided the pesticide is in its original, fully labeled container and still legal to use. If you cannot find someone who can use the pesticide and you no longer have a use for the product, below are options for disposing of an unwanted hazardous waste pesticide.

  • Registering as a large quantity generator (LQG) or small quantity generator (SQG) if 100 kg (220 pounds) or more of non-acute hazardous waste and 1 kg (2.2 pounds) or more of acute (P-listed) hazardous waste is generated in one month or accumulated at any one time. Table 1 below lists some acute and non-acute hazardous waste pesticides with their specific hazardous waste identification under the “RCRA #” column. Hazardous Waste Generator Registration, Reporting and Waste Fees - PUB2254 summarizes registration requirements.
  • If you have less than the above mentioned weight of hazardous waste pesticide you may be able to dispose of it as a conditionally exempt small quantity generator (CESQG). A fact sheet titled Managing Conditionally Exempt Small Quantities of Hazardous Waste - PUB0128. CESQGs may transport their own hazardous waste within Missouri. Under this standard a manifest or a licensed hazardous waste transporter is not required if you do not exceed the regulated amounts of waste. However, you will need to follow applicable U.S. Department of Transportation requirements for the waste being shipped.
  • Disposing of the hazardous waste pesticide under the universal waste rule in Missouri is an option that can reduce the regulatory burden on businesses allowing less stringent disposal requirements versus disposal under the more stringent hazardous waste regulations. The Universal Waste Rule in Missouri - PUB2058 summarizes the requirements of the rule.

Pesticide Container Disposal

In addition to label requirements, some pesticide containers must meet the requirements set forth in 40 CFR 261.7, Residues of Hazardous Wastes in Empty Containers, to be considered empty. Empty containers that once stored pesticide classified as acute hazardous waste versus containers that stored pesticide classified as non-acute hazardous waste may require different treatment methods for declaring the container empty. After the container is made empty according to label and 40 CFR 261.7 standards, the container should be punctured. Empty containers may be sent for recycling or placed in the trash and sent to a permitted solid waste landfill.

Ag Container Recycling Council is a non-profit organization that receives money from pesticide manufacturers to provide free pesticide container recycling programs throughout the United States. The Pesticide Container Management - PUB2727 includes more detail on managing empty pesticide containers.

Disposal of Pesticides Not Classified As Hazardous Waste

If you are absolutely certain the pesticide is not classified as a hazardous waste the pesticide may be solidified and placed into the sanitary landfill if the landfill chooses to accept it. However, because all pesticides are designed to prevent, destroy, repel or mitigate pests, disposal should be done in a professional manner preferably following the hazardous waste or universal waste laws and regulations.

A listing of the pesticides from 40 CFR 261.31 through 40 CFR 261.33 is provided below in Table 1. Please note the table may not include all hazardous waste pesticides. Table 1 includes various Hazardous Waste Codes (RCRA #) that have special meanings and are defined as follows:

F-List hazardous wastes from nonspecific sources (40 CFR 261.31)
P-List acutely toxic hazardous wastes from specific sources (40 CFR 261.33(e))
U-List toxic hazardous wastes and other commercial chemical products (40 CFR 261.33(f))
Toxicity characteristic hazardous wastes that meet or exceed the regulatory level listed in the table (as shown by laboratory analysis)

Table 1. Pesticides in parts 261.31 and 261.33

Pesticide/ChemicalCAS #RCRA #Toxicity Characteristic #Regulatory Level (mg/L)
1,1,1-Trichloroethane71-55-6U226  
2,4-D, Salts, Esters and AcidsVariousU240D016200.00
2,4,5-T, Salts, Esters and AcidsVariousF027  
A-Naphthylthiourea (ANTU)86-88-4P072  
Acrolein107-02-8P003  
Aldicarb116-06-3P070  
Aldrin309-00-2P004  
Allyl Alcohol107-18-6P005  
Aluminum Phosphide1302-45-0P006  
Aluminum Phosphide20859-73-8P006  
Aluminum Phosphide1302-45-0P006  
Amitrole61-82-5U011  
Arsenic Trioxide1327-53-3P012  
Arsenic Acid7778-39-4P010  
Arsenic Pentoxide1303-28-2P011  
Avitrol504-24-5P008  
Cacodylic Acid75-60-5U136  
Calcium Cyanide592-01-8P021  
Carbon Tetrachloride56-23-5U211  
Carbon Disulfide75-15-0P022  
Chlordane57-74-9U036D0200.03
Chlordecone143-50-0U142  
Chlorobenzene108-90-7U037D021100.00
Chlorobenzilate510-15-6U038  
D-D (1,2-Dichloropropane)8003-19-8U083  
DDD72-54-8U060  
DDT50-29-3U061  
Diallate2303-16-4U062  
Dibromochloropropane (DBCP)96-12-8U066  
Dieldrin60-57-1P037  
Dimethoate60-51-5P044  
Dinoseb88-85-7P020  
Disulfoton298-04-4P039  
Endosulfan115-29-7P050  
Endothall Disodium129-67-9P088  
Endrin72-20-8P051D0120.02
Erbon136-25-4F027  
Ethylene Dibromide106-93-4U067  
Famphur52-85-7P097  
Fluoracetamide/1081640-19-7P057  
Fluoracetamide640-19-7P057  
Formaldehyde50-00-0U122  
Furfural98-01-1U125  
Heptachlor76-48-8P059D0310.008
Hexachlorobenzene118-74-1U127  
Isodrin465-73-6P069  
Kepone143-50-0U142  
Lead Acetate301-04-2U144  
Lindane58-89-9U129D0130.4
Maleic Hydrazide123-33-1U148  
Methomyl16752-77-5P066  
Methoxychlor72-43-5U247D01410.0
Methyl Bromide74-83-9U029  
Methyl Parathion298-00-0P071  
Nicotine54-11-5P075  
Nitrobenzene98-95-3U169  
OMPA, Schradan152-16-9P085  
Orthodichlorobenzene95-50-1U070  
Paradichlorobenzene106-46-7U072  
Parathion56-38-2P089  
Pentachlorophenol, Salts7778-73-6F027  
Pentachlorophenol87-86-5U242D037100.00
Phenylmercuric Acetate (PMA)62-38-4P092  
Phorate298-02-2P094  
PMA62-38-4P092  
Potassium Cyanide151-50-8P098  
Procytox50-18-0U058  
Pronamide23950-58-5U192  
Safrole94-59-7U203  
Silvex, Salts, Acids and EstersVariousF027  
Sodium Cyanide143-33-9P106  
Sodium Pentachlorophenate131-52-2F027  
Sodium Fluoroacetate62-74-8P058  
Strychnine And Salts60-41-3P108  
Strychnine Alkaloid57-24-9P108  
Sulfotepp3689-24-5P109  
Thallium Sulfate7446-18-6P115  
Thiofanox39196-18-4P045  
Thiram137-26-8U244  
Toxaphene8001-35-2P123D0150.5
Warfarin81-81-2U248  
Wood Creosote8021-39-4U051  
Zinc Phosphide (<10%)1314-84-7U249  
Zinc Pentachlorophenate2917-32-0F027  
Zinophos297-97-2P040  

Additional Information


Nothing in this document may be used to implement any enforcement action or levy any penalty unless promulgated by rule under chapter 536 or authorized by statute.


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